Livia Brash is newly based in Melbourne, after being based in Germany for five years, where she was a member with Düsseldorf Lyric Opera, appeared as Sieglinde in Dramatic Voices Berlin's film of Die Walküre and was sponsored by the Wagner Society NSW.

Before the global pandemic, in 2019, Ms. Brash was one of twelve singers internationally to attend the prestigious Georg Solti Accademia in Italy, where she was under the tutelage of mentors such as Maestro Richard Bonynge AC CBE. She performed the title role of Bellini's Beatrice di Tenda as part of the London Bel Canto Festival with the London City Philharmonic Orchestra and appeared in recital in London. She was set to make her debut in title role of Verdi's Aida at the WIN Entertainment Centre Stadium in Australia (cancelled)

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In the 2018 season Ms. Brash made five role debuts, appearing in the title roles Alcina and Tosca, Mimi (La Bohème), and toured Australia as Rosina/Bertha swing (Il Barbiere di Siviglia). The same year, she also made solo appearances with the Canberra Symphony, Lake Macquarie Philharmonic, Willoughby Symphony and Central Coast Philharmonic orcehstras. She also won the Richard Bonynge Award in the 2018 Joan Sutherland and Richard Bonynge Bel Canto Competition.

She has performed in Austria with the AIMS Symphony Orchestra, with the Sydney Philharmonia Choirs and orchestra at City Recital Hall Sydney, was guest artist for the Canberra Choral Society and Canberra Wind Symphony for their Last Night at the Proms event at Albert Hall and performed at the Christmas Eve service at Sydney Town Hall.​ During her time as a Young Artist with Pacific Opera, she performed at the Sydney Opera House and the Chatswood Concourse.

In addition to her significant stage experience, Livia has also won several awards from Australia's most prestigious singing Competitions. She won the Opera Foundation for young Australians Dalwood-Wylie AIMS Award, and the AIMS Sundell Award, which allowed her to receive tuition at the Vienna State Opera. She also came third in the Joan Sutherland and Richard Bonynge Bel Canto Competition, as well as being named a finalist in the IFAC Handa Australian Singing Competition.

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Livia holds a Masters of Music Studies (Opera) from the Sydney Conservatorium of Music, where she was the recipient of the Geoffrey Rothwell Scholarship and the Joan Bonamy Scholarship.She completed a Bachelor of Music (Classical Voice) from the Australian National University.

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She has performed at numerous diplomatic and vice-regal events and has been featured in performances for Enlighten Festival, the Sydney Operatic Society, a sold-out concert concert for China’s Three Tenors in the Joan Sutherland Theatre at the Sydney Opera House, and Canberra Carols by Candlelight.